Page 117 - International safety guide for oil tankers and terminals
P. 117

FIRE-FIGHTING



                                        Some of the foams produced from concentrates are compatible with dry
                                        chemical powder and are suitable for combined use. The degree of
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                                        compatibility between the various foams, and between the different foams
                                        and dry chemical agents, varies and should be established by suitable
                                        tests.
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                                        The compatibility of foam compounds is a factor to be borne in mind
                                        when considering joint operations with other fire-fighters.

                                        Foam concentrates may deteriorate with time depending on the storage
                                        conditions. Storage at high temperatures and in contact with air will cause
                                        sludge and sediment to form. This may affect the extinguishing ability of
                                        the expanded foam. Samples of the foam concentrate should therefore be
                                        returned periodically to the manufacturer for testing and evaluation.


                              5.3.2.2 Carbon Dioxide
                                        Carbon dioxide is an effective smothering agent for extinguishing fires in
                                        enclosed spaces where it will not be widely diffused and where personnel
                                        can be evacuated quickly (e.g. machinery spaces, pumprooms and
                                        electrical switchboard rooms). Carbon dioxide is comparatively ineffective
                                        on an open deck or jetty area.

                                        Carbon dioxide will not damage delicate machinery or instruments and,
                                        being a non-conductor, can be used safely on or around electrical
                                        equipment even when it is energised. ึ

                                        Due to the possibility of static electricity generation, carbon dioxide
                                        should not be injected into any space containing an un-ignited flammable
                                        atmosphere.

                                        Carbon dioxide is asphyxiating and cannot be detected by sight or smell.
                                        All personnel should therefore evacuate the area before carbon dioxide is
                                        discharged. No one should then enter confined or partially confined
                                        spaces where carbon dioxide has been discharged unless supervised and
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                                        protected by suitable breathing apparatus and a lifeline. Canister type
                                        respirators should not be used. Any compartment that has been flooded
                                        with carbon dioxide must be fully ventilated before entry without breathing



                              5.3.2.3 Steam

                                        Steam is inefficient as a total smothering agent because of the
                                        substantial delay that may occur before sufficient air is displaced from an
                                        enclosure to render the atmosphere incapable of supporting combustion.
                                        Steam should not be injected into any space containing an un-ignited
                                        flammable atmosphere due to the possibility of static electricity
                                        generation. However, steam can be effective for fighting flange or similar
                                        fires when discharged from a lance type nozzle directly at a flange or joint
                                        leak, or a vent or similar fire.


                              5.3.2.4 Sand
                                        Sand is relatively ineffective as an extinguishing agent and is only useful
                                        for small fires on hard surfaces. Its primary use is to dry up small spills.










                                                   © ICS/OCIMF/IAPH 2006                                        83
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